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Microbial desulfurization of different coals.

C Acharya1, R N Kar, L B Sukla

  • 1Department of Biomineral and Biotechnology, Regional Research Laboratory, CSIR, Bhubaneswar, 751 013, India. celin_s@yahoo.com

Applied Biochemistry and Biotechnology
|August 12, 2004
PubMed
Summary

Microbial desulfurization using Acidithiobacillus sp. effectively removed high sulfur content from Indian and Polish coal. Optimal conditions achieved over 90% sulfur removal from lignite, but less from Assam coal due to organic sulfur and jarosite precipitation.

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Area of Science:

  • Environmental Science
  • Microbiology
  • Geochemistry

Background:

  • Coal combustion releases sulfur dioxide, a major air pollutant.
  • High-sulfur coal presents significant environmental challenges in thermal power generation.
  • Microbial desulfurization offers a promising alternative for reducing sulfur emissions.

Purpose of the Study:

  • To investigate the efficacy of microbial methods for removing sulfur from high-sulfur coal samples.
  • To optimize conditions for maximizing sulfur removal using Acidithiobacillus sp.
  • To analyze factors affecting desulfurization efficiency in different coal types.

Main Methods:

  • Desulfurization of three high-sulfur coal samples (Assam, Rajasthan, Poland) using indigenous Acidithiobacillus sp.
  • Optimization of parameters including initial pH, particle size, pulp density, incubation period, temperature, ferrous sulfate concentration, and agitation.
  • Photomicrographic studies to demonstrate sulfur removal.

Main Results:

  • Maximum total sulfur removal achieved: 91.87% for lignite, 63.13% for Polish coal, and 9.44% for Assam coal.
  • Optimal conditions identified: pH 1.5, 45-micron particle size, 2% pulp density, 30-day incubation at -35°C, 44.2 g/L ferrous sulfate, 140 rpm shaking.
  • Lower efficiency for Assam coal attributed to jarosite precipitation and high organic sulfur content.

Conclusions:

  • Microbial desulfurization with Acidithiobacillus sp. is effective for certain high-sulfur coals.
  • Coal characteristics, such as organic sulfur content and mineral precipitation, significantly impact microbial desulfurization efficiency.
  • Further research is needed to enhance sulfur removal from coals with challenging compositions.