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Silenes as novel synthetic reagents: identification of a practical method for silene generation and trapping

Malcolm B Berry1, Russell J Griffiths, Mahesh J Sanganee

  • 1Department of Chemistry, University of Durham, Science Laboratories, South Road, Durham, UK DH1 3LE.

Organic & Biomolecular Chemistry
|August 12, 2004
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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.