Related Experiment Video
Updated: Aug 23, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Characteristics of monolayer behavior and multilayer film structures of comb polymers having different kinds of
Atsuhiro Fujimori1, Hiroo Nakahara, Eisuke Ito
1Department of Chemistry, Faculty of Science, Saitama University, Shimo-okubo 255, Sakura-ku, Saitama 338-8570, Japan.
Abstract:
With comb polymers with different kinds of fluorocarbon side-chains, significant effects of spreading solvents on the monolayers at the air/water interface and the molecular arrangement in the deposited films could be found by the use of trifluoroacetic acid and its mixed solvents with n-hexane, depending on the atoms, fluorine or hydrogen, substituted at the end of the fluorocarbon side-chains. These facts are probably due to intralayer hydrogen bonding cooperating with the carbonyl groups of the long-chain esters. The deposited films of solid substrates were characterized by polarized near-edge X-ray absorption fine structure (NEXAFS) spectroscopy as well as in-plane X-ray diffraction and scanning electron and atomic force microscopy.
More Related Videos
Related Concept Videos
Polymer Classification: Architecture
Characteristics and Nomenclature of Copolymers
Characteristics and Nomenclature of Homopolymers
Polymer Classification: Stereospecificity
Molecular Shape and Polarity
Polymers

