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Updated: Aug 22, 2026

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Structure determination of isolated metal clusters via far-infrared spectroscopy
André Fielicke1, Andrei Kirilyuk, Christian Ratsch
1FOM Institute for Plasma Physics Rijnhuizen, Edisonbaan 14, NL-3439 MN Nieuwegein, The Netherlands.
Abstract:
We present a new method for the size selective structure determination of small isolated metal clusters in the gas phase. The technique is applied to cationic vanadium clusters containing 6 to 23 atoms, whose far infrared absorption spectra are measured in the 140-450 cm(-1) spectral range. The spectra are unique for each cluster size and are true fingerprints of the cluster's structure. By comparing the experimental spectra to spectra obtained from density-functional theory, the geometric cluster structure can be identified.
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