Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Heterometallic lanthanide group 12 metal iodides.

Louise Huebner1, Anna Kornienko, Thomas J Emge

  • 1Department of Chemistry and Chemical Biology, Rutgers, the State University of New Jersey, 610 Taylor Road, Piscataway, NJ 08854-8087, USA.

Inorganic Chemistry
|August 31, 2004
PubMed
Summary

Neodymium tri-iodide reacts with Group 12 metal iodides, forming new heterometallic compounds. Structural differences depend on metal-ligand bond strengths, impacting lanthanide iodide applications.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Polymorph-Dependent Photophysics of Blue-Emitting Brominated Organic Crystals.

ACS applied optical materials·2026
Same author

A metal-metal quadruply bonded dimer of two pincer-ligated metal centers.

Dalton transactions (Cambridge, England : 2003)·2026
Same author

Olefin Coupling Catalyzed by (Pybox)Os Complexes via Osmacyclopentane Intermediates: Comparison with Isoelectronic (Phebox)Ir.

JACS Au·2025
Same author

Dinitrogen reduction to ammonia with a pincer-Mo complex: new insights into the mechanism of nitride-to-ammonia conversion.

Chemical science·2025
Same author

Alkane Dehydrogenation and H/D Exchange by a Cationic Pincer-Ir(III) Hydride: Cooperative C-H Addition and β-H Elimination Modes Induce Anomalous Selectivity.

Journal of the American Chemical Society·2025
Same author

Using Host-Guest Chemistry to Examine the Effects of Porosity and Catalyst-Support Interactions on CO<sub>2</sub> Reduction.

Angewandte Chemie (International ed. in English)·2025

Area of Science:

  • Inorganic Chemistry
  • Materials Science
  • Lanthanide Chemistry

Background:

  • Lanthanide iodides are explored for applications in catalysis and materials.
  • Understanding their reactivity with other metal halides is crucial for developing new compounds.

Purpose of the Study:

  • To investigate the reactions between neodymium tri-iodide and Group 12 metal iodides (Zn, Cd, Hg).
  • To characterize the resulting heterometallic compounds and understand their structural determinants.
  • To explore the behavior of ytterbium tri-iodide under similar conditions.

Main Methods:

  • Synthesis of heterometallic compounds by reacting neodymium tri-iodide with Group 12 metal iodides.
  • Structural characterization of the synthesized compounds using X-ray diffraction.

Related Experiment Videos

  • Investigation of ytterbium tri-iodide reactions in the presence of excess iodide and in pyridine solvent.

    • Main Results:

    • Formation of ionic and charge-neutral heterometallic compounds, such as [(THF)(5)NdI(2)][MI(3)THF] and [(THF)(5)NdI(micro(2)I)HgI(3)].
    • Structural variations are attributed to M-L bond strengths rather than Nd-L bonds.
    • Ytterbium tri-iodide readily forms triiodide salts or iodide salts with pyridine, indicating facile iodide displacement.

    Conclusions:

    • The reactivity of lanthanide iodides with Group 12 metal iodides leads to diverse heterometallic structures.
    • Metal-ligand bond strengths are key factors in determining the resulting compound structures.
    • Lanthanide iodides are prone to iodide displacement, complicating their use as Lewis acid catalysts.