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Mono- and bis(tetrathiafulvaleno)hexadehydro[12]annulenes
Kenji Hara1, Masashi Hasegawa, Yoshiyuki Kuwatani
1Department of Chemistry, Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192-0397, Japan.
Abstract:
Hexadehydro[12]annulenes annelated with one or two TTF units have been synthesized to investigate their pi-amphoteric properties based on the TTF and [12]annulene moieties; these compounds show multi-redox potentials, solvatochromism and the formation of large sandwich complexes.