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Updated: Aug 22, 2026

Using Cyclic Voltammetry, UV-Vis-NIR, and EPR Spectroelectrochemistry to Analyze Organic Compounds
Published on: October 18, 2018
Seasoning materials chemistry by using a well-matured organic concept
1Department of Advanced Materials Chemistry, Graduate School of Engineering, Yokohama National University, 79-5, Tokiwadai, Hodogaya, Yokohama, 240-8501, Japan. yyokoyam@ynu.ac.jp
Abstract:
The concept "introduction of allylic 1,3-strain (A(1,3)-strain) to photochromism" originated from the experience of total synthesis of natural products about 18 years ago, when the author was a post doc. It was first applied to synthetic organic reactions, then it was successfully employed in the diastereoselective photochromic reactions of diarylethenes. A diastereomeric excess of the photoreaction was 88 % for the first example, and it was improved to 94 % by the recent operation of rational molecular tailoring.
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