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Published on: December 7, 2015
Discontinuous tangential stress in double wall carbon nanotubes
P Puech1, H Hubel, D J Dunstan
1Laboratoire Physique des Solides de Toulouse UMR-CNRS 5477, IRSAMC, Université Paul Sabatier, 118 Route de Narbonne, 31062 Toulouse, France. Pascal.Puech@lpst.ups-tlse.fr
We studied double wall carbon nanotubes under high pressure. The inner tube shows less stress response and stable phonon bands, unlike the outer tube, explained by a new elastic model.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Nanotechnology
Background:
- Double-wall carbon nanotubes (DWCNTs) are advanced nanomaterials with unique mechanical and electronic properties.
- Understanding their behavior under extreme conditions, such as high hydrostatic pressure, is crucial for potential applications.
Purpose of the Study:
- To investigate the stability and mechanical response of DWCNTs under hydrostatic pressures up to 10 GPa.
- To analyze the pressure-dependent behavior of phonon modes in both the inner and outer tubes of DWCNTs.
Main Methods:
- Inelastic light scattering was employed to observe the tangential optical phonon mode.
- Hydrostatic pressures up to 10 GPa were applied to the DWCNT samples.
- The elastic continuum shell model was utilized to interpret the experimental results.
Main Results:
- The tangential optical phonon mode splits, showing distinct responses for the external and internal tubes.
- The internal tube exhibits a 45% smaller pressure coefficient compared to the external tube and single-wall carbon nanotubes.
- The external tube's phonon band broadens with pressure, while the internal tube's remains constant.
Conclusions:
- The contrasting pressure responses of the inner and outer tubes are attributed to distinct stress components.
- The elastic continuum shell model successfully explains the observed pressure-dependent phonon shifts and line broadening.
- These findings provide insights into the mechanical properties and stability of DWCNTs under pressure.
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The process begins by slicing the tube at critical points and analyzing the internal forces and stress components at these sections, focusing on the centroid. Normal stresses, generated by axial forces and bending moments, are either compressive or tensile and vary across the section from...

