Multi-component kinetics of activated sludge treatment of bleached kraft mill effluent

This study investigated the discrepancies between the BOD removal rates measured during short term assays and those measured during continuous activated sludge treatment of bleached kraft mill effluent (BKME). A combination of batch tests and fed batch tests with oxygen uptake rate (OUR), chemical oxygen demand (COD), biochemical oxygen demand (BOD), and mixed liquor volatile suspended solids (MLVSS) measurements were used to characterize the degradation rates for the activated sludge treatment of BKME and to divide the soluble readily biodegradable substrate into two to five separate fractions based on biodegradation rates. The removal rates varied by over an order of magnitude between the most readily degradable substrates (1 x 10(-3) mg COD/mg MLVSS minute), and the more slowly degradable substrates (2 x 10(-5) mg COD/mg MLVSS minute). If the readily biodegradable fraction of BKME was modeled as one substrate, initial rate kinetic measurements from batch tests were heavily influenced by the fractions with the greatest degradation rates, while any remaining BOD in the treated effluent was predominantly from the slowly degradable fraction, giving inconsistent results. Taking the multi-component nature of the wastewater into account, batch test results can be used to predict fed-batch and continuous activated sludge reactor performance.