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Updated: Aug 21, 2026

Optimization of Crystal Growth for Neutron Macromolecular Crystallography
Published on: March 13, 2021
Domain wall propagation and nucleation in a metastable two-level system
Hans C Fogedby1, John Hertz, Axel Svane
1Institute of Physics and Astronomy, University of Aarhus, DK-8000 Aarhus C, Denmark. fogedby@phys.au.dk
Abstract:
We present a dynamical description and analysis of nonequilibrium transitions in the noisy one-dimensional Ginzburg-Landau equation for an extensive system based on a weak noise canonical phase space formulation of the Freidlin-Wentzel or Martin-Siggia-Rose methods. We derive propagating nonlinear domain wall or soliton solutions of the resulting canonical field equations with superimposed diffusive modes. The transition pathways are characterized by the nucleation and subsequent propagation of domain walls. We discuss the general switching scenario in terms of a dilute gas of propagating domain walls and evaluate the Arrhenius factor in terms of the associated action. We find excellent agreement with recent numerical optimization studies.
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