Related Experiment Video
Updated: Aug 8, 2026

08:51
Coulomb Explosion Imaging as a Tool to Distinguish Between Stereoisomers
Published on: August 18, 2017
Kinetic electron excitation in atomic collision cascades
1Institute of Experimental Physics, University of Duisburg-Essen, 45117 Essen, Germany.
Physical Review Letters
|November 5, 2004
Summary
Energetic ions create hot electrons in solids, detected via a metal-insulator-metal junction. This method offers new insights into internal excitation spectroscopy, unlike traditional electron emission studies.
Area of Science:
- Solid-state physics
- Materials science
- Surface science
Background:
- Investigating electron excitation mechanisms in solids is crucial for understanding material properties.
- Traditional electron emission studies have limitations in probing certain excitation pathways.
- Energetic ion bombardment offers a unique method to induce electronic excitations.
Purpose of the Study:
- To investigate the kinetic excitation of electrons in solids upon energetic ion bombardment.
- To explore a novel method for detecting hot electrons with excitation energies below the vacuum level.
- To establish the potential of this technique for internal excitation spectroscopy.
Main Methods:
- Utilizing a metal-insulator-metal (MIM) junction device.
- Bombarding the solid surface with energetic ions.
- Detecting the resulting hot electrons and measuring the tunneling current.
Main Results:
- Hot electrons were successfully detected with excitation energies below the vacuum level.
- The observed tunneling current showed a dependence on projectile energy.
- The tunneling current was also found to be dependent on the applied bias voltage across the MIM junction.
Conclusions:
- The MIM junction method provides access to information not obtainable through conventional electron emission experiments.
- The observed dependencies suggest the potential for internal excitation spectroscopy.
- This technique opens new avenues for probing electronic excitation processes in materials.
Related Concept Videos
Photoelectric Effect
When light of a particular wavelength strikes a metal surface, electrons are emitted. This is called the photoelectric effect. The minimum frequency of light that can cause such emission of electrons is called the threshold frequency, which is specific to the metal. Light with a frequency lower than the threshold frequency, even if it is of high intensity, cannot initiate the emission of electrons. However, when the frequency is higher than the threshold value, the number of electrons ejected...
The Bohr Model
Following the work of Ernest Rutherford and his colleagues in the early twentieth century, the picture of atoms consisting of tiny dense nuclei surrounded by lighter and even tinier electrons continually moving about the nucleus was well established. This picture was called the planetary model since it pictured the atom as a miniature “solar system” with the electrons orbiting the nucleus like planets orbiting the sun. The simplest atom is hydrogen, consisting of a single proton as the nucleus...
Mass Spectrometry: Molecular Fragmentation Overview
The ionization of a molecule into a molecular ion inside the mass spectrometer causes instability in the molecule's structure due to the loss of an electron. This eventually leads to the fragmentation or breaking of some bonds in the molecule. The fragmentation occurs predominantly at specific bonds to yield relatively stable fragments.
One type of fragmentation pattern is the cleavage of a single bond in the molecular ion. The cleavage leads to a radical and a cation. The cleavage can occur at...
One type of fragmentation pattern is the cleavage of a single bond in the molecular ion. The cleavage leads to a radical and a cation. The cleavage can occur at...
Types of Collisions - II
When two or more objects collide with each other, they can stick together to form one single composite object (after collision). The total mass of the object after the collision is the sum of the masses of the original objects, and it moves with a velocity dictated by the conservation of momentum. Although the system's total momentum remains constant, the kinetic energy decreases, and thus such a collision is an inelastic collision. Most of the collisions between objects in daily life are...
Deactivation Processes: Jablonski Diagram
Luminescence, the emission of light by a substance that has absorbed energy, is a process that involves the interaction of molecules with light. The energy-level diagram, or Jablonski diagram, is a graphical representation of these interactions, illustrating the various states and transitions a molecule can undergo. In a typical Jablonski diagram, the lowest horizontal line represents the ground-state energy of the molecule, which is usually a singlet state. This state represents the energies...
Atomic Emission Spectroscopy: Overview
Atomic emission spectroscopy (AES) is an analytical technique used to determine the elemental composition of a sample by analyzing the light emitted from excited atoms. In AES, atoms in a sample are excited to higher energy levels by thermal energy from high-temperature sources, such as plasma, arcs, or sparks. When these excited atoms return to lower energy states, they emit light at specific wavelengths characteristic of each element. The resulting atomic emission spectrum, which consists of...

