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Extruding foams from corn starch acetate and native corn starch
1University of Nebraska-Lincoln, Industrial Agricultural Products Center, 208 L.W. Chase Hall, Lincoln, Nebraska 68583-0730, USA.
Biomacromolecules
|November 9, 2004
Summary
This study reduced the hydrophilicity and cost of starch foams by blending native corn starch with starch acetate. Extrusion processing optimized conditions for improved foam properties, including lower water absorption.
Area of Science:
- Materials Science
- Polymer Science
- Food Science
Background:
- Native starch foams exhibit hydrophilicity, limiting their applications.
- The cost associated with modifying starch further restricts the use of starch-based foams.
Purpose of the Study:
- To decrease the hydrophilicity and cost of starch foams.
- To investigate the effects of blending native corn starch with starch acetate and extrusion processing on foam properties.
Main Methods:
- Native corn starch was blended with starch acetate.
- Foams were produced using a twin-screw mixing extruder.
- Optimized processing parameters including native starch content, screw speed, and barrel temperature were determined.
Main Results:
- Extrusion processing significantly affected starch molecular degradation.
- The melting temperature of the extruded starch acetate/native starch foam (216°C) was higher than starch acetate (193.4°C).
- New crystalline regions were formed in the extruded foam, indicated by X-ray diffractograms.
- Optimal conditions (46.0% native starch, 163 rpm, 148°C) yielded high radial expansion, high compressibility, low specific mechanical energy, and low water absorption.
Conclusions:
- Blending native corn starch with starch acetate and employing extrusion is an effective method to reduce hydrophilicity and cost.
- Optimized processing parameters enhance key physical and mechanical properties of starch foams.
- This approach offers a viable route for expanding the applications of starch-based foams.