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Frame transformation relations for fluxional symmetric rotor dimers
Horace T Crogman1, William G Harter
1Department of Physics, University of Arkansas, Fayetteville, Arkansas 72701, USA.
Abstract:
The theory of frame transformation relation connecting body oriented angular momentum states and lab weakly coupled momentum states have been extended from rotor-electron to rotor-dimer systems. Coupling schemes are analyzed for weak and strong cases of correlation between lab and two different rotor body frames. It is shown that the frame transformation relation is a purely quantum effect at low angular momentum but an approach to a classical limit for high J. Symmetry analysis of frame transformation is compared to eigensolutions of model coupling Hamiltonian.
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