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11:44
Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
Published on: March 20, 2014
Controlling stereochemistry during oxidative coupling. Preparation of Rp or Sp phosphoramidates from one P-chiral
Johan Nilsson1, Jacek Stawinski
1Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Sweden.
Chemical Communications (Cambridge, England)
|November 16, 2004
Abstract:
Stereochemical outcome of oxidative coupling of H-phosphonate diesters with amines, promoted by iodine, can be controlled to obtain the corresponding phosphoramidate diesters with inversion or with retention of configuration at the phosphorus centre.
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