Arsenic and lead leaching from the waste derived fertilizer ironite

The toxicity characteristic leaching procedure (TCLP) and the synthetic precipitation leaching procedure (SPLP) were performed on commercially purchased samples of the waste-derived soil amendment marketed as Ironite. Ten samples of the 1-0-0 grade (the most widely available in Florida) were tested. Two samples of the 12-10-10 grade and three samples of the 6-2-1 grade (a liquid version) were tested as well. TCLP leachate concentrations from the 1-0-0 grade samples ranged from 5.0 to 8.0 mg L(-1) for lead and 2.2 to 4.8 mg L(-1) for arsenic. SPLP concentrations from the 1-0-0 samples ranged from 0.62 to 3.1 mg L(-1) for lead and 1.9 to 8.2 mg L(-1) for arsenic. All of the 1-0-0 grade samples exceeded the U.S. hazardous waste toxicity characteristic (TC) limit for lead (5 mg L(-1)), while five of the 10 SPLP samples exceeded the TC limit for arsenic (5 mg L(-1)). The greater arsenic leachability in the SPLP relative to the TCLP was determined to be a result of lower pH conditions in the SPLP. A composite sample of the 1-0-0 grade was found to leach much greater concentrations of both arsenic and lead using California's waste extraction test (WET). Lead leachate concentrations were much lower in the two 12-10-10 samples (0.03 mg L(-1) or less); arsenic concentrations in these leachates (both TCLP and SPLP) exceeded 5 mg L(-1). None of the 6-2-1 samples contained lead or arsenic above TC limits. An experiment performed on the 1-0-0 grade which examined leachability as a function of pH found that at pH values in the range of what is encountered in the human digestive system (pH 4.0 to 1.5) lead leached 2-36% of its initial content, and arsenic leached 1-6% of its initial content. A simple gastric acid leaching experiment found 83 and 37% of the lead and arsenic present to leach, respectively.