Orientational dynamics of hydrogen-bonded phenol

Y L A Rezus1, D Madsen, H J Bakker

  • 1FOM-institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands. rezus@amolf.nl

Summary

Hydrogen bonding significantly alters molecular reorientation dynamics. Femtosecond spectroscopy reveals that acetone-bound phenol-d exhibits frequency-dependent orientational changes, unlike free phenol-d.

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