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![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Chlorobis[N-ethoxycarbonyl-N'-(p-methoxyphenyl)thiourea-kappaS]copper(I)
Bi-Quan Su1, Liang Xian, Hai-Bin Song
1School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, People's Republic of China. subq@mail.lzjtu.cn
Abstract:
The title copper(I) complex, [CuCl(C(11)H(14)N(2)O(3)S)(2)], was synthesized by the redox reaction of cupric chloride with the corresponding thiourea derivative as reducing agent. The Cu(I) coordination environment is trigonal planar, involving two S atoms and one Cl atom. The presence of intramolecular hydrogen bonds leads to the formation of a cis conformation and promotes the stability of the complex.
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