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Updated: Jul 10, 2026

Fabrication of Ultra-thin Color Films with Highly Absorbing Media Using Oblique Angle Deposition
Published on: August 29, 2017
Self-assembled electrooptic thin films with remarkably blue-shifted optical absorption based on an X-shaped
Hu Kang1, Peiwang Zhu, Yu Yang
1Department of Chemistry and the Materials Research Center, Northwestern University, Evanston, Illinois 60208-3113, USA.
Abstract:
An "X-shaped" two-dimensional electrooptic (EO) chromophore with extended orthogonal conjugation was designed and synthesized. Self-assembled thin films of this chromophore were fabricated via layer-by-layer chemisorptive siloxane-based self-assembly. The films exhibit a dramatically blue-shifted optical maximum (325 nm) while maintaining a large EO response (chi33(2) approximately 232 pm/V at 1064 nm; r33 approximately 43 pm/V at 1550 nm).
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