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Published on: January 7, 2019
Determination of low amounts of long-chain branches in polypropylene using a combination of chromatographic and
Beate Krause1, Dieter Voigt, Albena Lederer
1Leibniz-Institute of Polymer Research Dresden, Hohe Strasse 6, Dresden 01069, Germany. krause-beate@ipfdd.de
Abstract:
The focus of our investigations lies on the detection of low amounts of long-chain branching (LCB) in isotactic polypropylene (iPP) created by electron beam irradiation. The modified samples were investigated by rheological experiments in shear and elongational flow and by size-exclusion chromatography. The comparison of the results demonstrates the efficiency and the detection limits of these methods, particularly at very low degrees of long-chain branching. The combination of chromatographic and rheological methods enables a sensitive and comprehensive way for the characterisation of the long-chain branching phenomena.
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