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Nondivergent classical response functions from uncertainty principle: quasiperiodic systems
1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
The Journal of Chemical Physics
|January 11, 2005
Summary
Phase-space averaging resolves time-divergence in classical response functions for quasiperiodic systems. This method aligns classical and quantum mechanics, enhancing understanding of system dynamics.
Area of Science:
- Quantum mechanics
- Statistical mechanics
- Classical dynamics
Background:
- Classical response functions often exhibit time-divergence.
- Establishing classical-quantum correspondence is crucial for understanding complex systems.
Purpose of the Study:
- To resolve time-divergence in classical response functions.
- To establish classical-quantum correspondence for quasiperiodic systems.
Main Methods:
- Phase-space averaging within the quantized uncertainty volume O(hn).
- Replacing microcanonical distribution density with quantized uniform distribution density.
- Numerical calculations for one- and two-dimensional systems.
Main Results:
- Time-divergence in linear and nonlinear classical response functions is eliminated.
- Agreement between quantum and classical expressions is achieved via Heisenberg's correspondence principle.
- Numerical results demonstrate good agreement between quantum and classical calculations.
Conclusions:
- Phase-space averaging within the quantized uncertainty volume is a viable method for classical-quantum correspondence.
- The approach is generalizable to systems with N degrees of freedom.
- This method provides a robust framework for studying response functions in quasiperiodic systems.