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![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Di-mu-iodo-bis{[1,1'-methylenebis(3,5-dimethyl-1H-pyrazole-kappaN2)]copper(I)}
Ying Xu1, Hong Xi Li, Wen Hua Zhang
1Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, Jiangsu, People's Republic of China.
Abstract:
In the title compound, [Cu2I2(C11H16N4)2], each of the two crystallographically equivalent Cu atoms is tetrahedrally coordinated by two N atoms from one 1,1'-methylenebis(3,5-dimethyl-1H-pyrazole) ligand and two bridging iodide anions. The molecule has a crystallographic center of symmetry located at the mid-point of the Cu...Cu line. One H atom of the CH2 group of the 1,1'-methylenebis(3,5-dimethyl-1H-pyrazole) ligand interacts with an iodide ion in an adjacent molecule to afford pairwise intermolecular C-H...I contacts, thereby forming chains of molecules running along the [101] direction.
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