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Synthesis and characterisation of two monomeric crystalline thallium(I) beta-diketiminates
Yanxiang Cheng1, Peter B Hitchcock, Michael F Lappert
1Chemistry Department, University of Sussex, Brighton, BN1 9QJ, UK.
Chemical Communications (Cambridge, England)
|February 3, 2005
Abstract:
Treatment of the appropriate sodium beta-diketiminate NaL or NaL' with an equivalent portion of TlCl in thf under mild conditions furnishes in good yield the first structurally characterised thallium beta-diketiminates: the monomeric, orange, crystalline Tl(I) complexes TlL and TlL' [L = {N(SiMe3)C(Ph)}2CH, L' = {N(C6H3Pr(i)(2)-2,6)C(H)}2CPh].
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