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Speciation of volatile selenium species in plants using gas chromatography/inductively coupled plasma mass
Juris Meija1, Maria Montes-Bayón, Joseph A Caruso
1Department of Chemistry, University of Cincinnati, Cincinnati, OH 45221-0172, USA.
Abstract:
Gas chromatography/inductively coupled plasma mass spectrometry (GC/ICP-MS) coupled with solid phase micro-extraction can provide a simple, extremely selective and sensitive technique for the analysis of volatile sulfur and selenium compounds in the headspace of growing plants. In this work, the technique was used to evaluate the volatilization of selenium in wild-type and genetically-modified Brassica juncea seedlings. By converting toxic inorganic selenium in the soil to less toxic, volatile organic selenium, B. juncea might be useful in bioremediation of selenium contaminated soil.
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