Structures and dynamics of thermosensitive microgel suspensions studied with three-dimensional cross-correlated light...

The structure factors, short- and long-time diffusion coefficients, and hydrodynamic interactions of concentrated poly(N-isopropylacryamide) microgel suspensions were measured with simultaneous static and dynamic three-dimensional cross-correlated light scattering. The data are interpreted through comparison to hard sphere theory. The structure factors are known to be described well by the hard sphere approximation. When the structure factor is fit to an effective hard sphere volume fraction and radius, the diffusion and hydrodynamic interactions are also well described by the hard sphere model. We demonstrate that one single hard sphere volume fraction is sufficient to describe the microgel structures, hydrodynamic interactions, and long- and short-time collective diffusion coefficients. This result is surprising because the particle form of the microgels at these temperatures is not rigid, but rather "fuzzy" spheres with dangling polymer chains.