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Updated: Aug 19, 2026

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Published on: December 1, 2020
Neutron scattering study of the H-bond network in amorphous N-methylformamide
Férid Hammami1, Salah Nasr, Marie-Claire Bellissent-Funel
1Laboratoire Physico-Chimie des Matériaux, Département de Physique, Faculté des Sciences de Monastir, Monastir 5019, Tunisia.
Abstract:
Original investigations of structural properties in noncrystalline solid N-methylformamide (HCONHCH(3)) are presented in this paper. After description of the sample preparation, the elastic neutron scattering formalism is applied to deduce the coherent scattering cross section for amorphous N-methylformamide. The contribution of each possible monomer (cis or trans) is computed and the corresponding distinct structure factor is deduced. Our measurements clearly show that the hydrogen-bond network occurs in amorphous N-methylformamide between C=O and N-H groups. The experimental spectra are consistent with an open-chain structure similar to the one existing in the crystalline form. The more probable clusters that have been identified in the liquid are also examined.
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