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Disulfido metal carbonyl complexes containing manganese
Richard D Adams1, O-Sung Kwon, Shaobin Miao
1Department of Chemistry and Biochemistry and the USC NanoCenter, University of South Carolina, Columbia, SC 29208, USA. Adams@mail.chem.sc.edu
Accounts of Chemical Research
|March 16, 2005
Summary
Recent studies explore new disulfido manganese carbonyl complexes. Research covers ligand coordination, manganese atom reactions, and disulfido ligand insertion reactions, advancing inorganic chemistry.
Area of Science:
- Inorganic Chemistry
- Organometallic Chemistry
Background:
- Disulfido ligands are crucial in coordination chemistry.
- Manganese carbonyl complexes offer diverse reactivity.
Purpose of the Study:
- To present recent studies on new disulfido metal carbonyl complexes containing manganese.
- To discuss the coordination chemistry, reactivity, and insertion reactions of these complexes.
Main Methods:
- Review of recent literature on manganese-disulfido chemistry.
- Analysis of structural and reactive properties.
Main Results:
- Detailed discussion on the coordination modes of disulfido ligands.
- Elucidation of reactions occurring at the manganese center.
- Characterization of insertion reactions within the disulfido bridge.
Conclusions:
- These complexes exhibit unique reactivity patterns.
- Understanding their chemistry provides insights into sulfur-metal bonding.
- Further research can lead to novel catalytic applications.