A hydrophobic nanocapsule controls the photophysics of aromatic molecules by suppressing their favored solution
Lakshmi S Kaanumalle1, Corinne L D Gibb, Bruce C Gibb
1Department of Chemistry, University of Miami, Coral Gables, Florida 33124, USA.
Journal of the American Chemical Society
|March 18, 2005
Abstract:
A combination of hydrophobic forces and guest templation drive the assembly of cavitands into molecular capsules. Remarkably, anthracene that dimerizes with unit efficiency in solution does not dimerize within the capsule despite forming 2:2 complex. The capsule allows an unprecedented examination of the anthracene excimer.
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