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Updated: Aug 19, 2026

Synthesis of Terpolymers at Mild Temperatures Using Dynamic Sulfur Bonds in Poly(S-Divinylbenzene)
Published on: May 20, 2019
Calorimetric and computational study of sulfur-containing six-membered rings
Eusebio Juaristi1, Rafael Notario, Maria Victoria Roux
1Departamento de Quimica, Centro de Investigacion y de Estudios Avanzados del Instituto Politecnico Nacional, Apartado Postal 14-740, 07000 Mexico, D.F., Mexico. juaristi@relaq.mx
Abstract:
Thermochemical data, and in particular the enthalpies of formation of oxygen- and sulfur-containing six-membered heterocycles provide essential information on the factors responsible for the contrasting behavior (structural, conformational and reactivity) between these types of compounds. A proper understanding of the experimental observations requires theoretical modeling in order to confirm the relative importance of the steric, electronic, electrostatic and stereoelectronic interactions that are responsible of the enthalpies of formation for the heterocyclic compounds of interest.
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