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Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
Window effect in a discretized model for diffusion of a chain in one dimension
G Terranova1, C M Aldao, H O Mártin
1Physics Department, School of Exact and Natural Sciences, University of Mar del Plata, Deán Funes 3350, 7600 Mar del Plata, Argentina.
Abstract:
We introduce a model to study the diffusion of chains in microporous solids. The difficulties a chain has to escape from a pore where it is confined is found to strongly depend on the ratio between the chain length and the cage size. This dynamic effect implies a nonstandard behavior of the diffusion coefficient. We found a window effect that can be explained without using any energy argument.
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