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Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Magnetic instabilities in Fe3C cementite particles observed with Fe K-edge x-ray circular dichroism under pressure
E Duman1, M Acet, E F Wassermann
1Experimentalphysik, Universität Duisburg-Essen, D-47048 Duisburg, Germany.
Abstract:
The ferromagnetic interstitial iron compound Fe(3)C (cementite) is expected to have Invar properties, whereby a high-moment to low-moment transition should occur when the atomic volume is reduced below a critical value. We, therefore, examine the pressure dependence of the Fe K-edge x-ray magnetic circular dichroism in Fe(3)C at ambient temperature and pressures up to 20 GPa. We find clear evidence for a high-moment to low-moment transition around 10 GPa.
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