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Updated: Aug 7, 2026

Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR
Published on: December 16, 2013
Orientation of single crystals using linear approximations to NMR transits
Young-Sik Kye1, Xingang Zhao, Gerard S Harbison
1Department of Chemistry, University of Nebraska at Lincoln, Lincoln, NE 68588-0304, USA.
Abstract:
We have derived analytical expressions for determining the orientation of high-symmetry single crystals from line-crossings in a single rotation plot. We demonstrate the utility of the method using the strontium-87 resonance in strontium nitrate. Employing our new method, which we call orientation of single crystals using linear approximations to NMR transits (OSCULANT), in combination with fourth-order perturbation theory, we obtain a highly accurate value for the quadrupole coupling constant, and an estimate for the chemical shielding anisotropy.
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