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Related Experiment Videos

[Study on magnesium ionization in cathodic sputtering glow discharge plasma].

J You1, Z Wang, G Zhang

  • 1Shanghai Enhanced Laboratory of Ferrometallurgy, Shanghai University, 200072 Shanghai.

Guang Pu Xue Yu Guang Pu Fen Xi = Guang Pu
|April 13, 2005
PubMed
Summary

A new method corrects analytical curves in cathodic sputtering glow discharge (CSGD) plasma by accounting for magnesium ion influence. This improves accuracy for aluminum-magnesium alloy analysis.

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Area of Science:

  • Analytical Chemistry
  • Atomic Spectroscopy
  • Plasma Physics

Context:

  • Cathodic sputtering glow discharge (CSGD) is a plasma source used in atomic absorption spectroscopy.
  • Aluminum-magnesium alloys present challenges in CSGD analysis due to magnesium ionization.
  • Existing analytical methods may be affected by plasma conditions and ion abundance.

Purpose:

  • To propose a novel method for correcting analytical working curves in CSGD plasma.
  • To investigate the influence of magnesium ions on the accuracy of atomic absorption measurements.
  • To understand and quantify the factors affecting magnesium ionization degree in CSGD.

Summary:

  • A method is presented utilizing Doppler broadening-dependent absorption width and the ratio of atomic to ionic absorbance to assess ionization degree in CSGD plasma.

Related Experiment Videos

  • Experimental results demonstrate that abundant magnesium ions significantly impact analytical curves under conventional conditions.
  • A corrected method is derived, and factors contributing to magnesium ionization are discussed.
  • Impact:

    • Enhances the accuracy and reliability of quantitative analysis for aluminum-magnesium alloys using CSGD.
    • Provides a means to compensate for plasma-induced interferences in spectrochemical analysis.
    • Contributes to a deeper understanding of plasma-analyte interactions in sputtering discharges.