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Updated: Jul 13, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Synthesis and characterization of mono beta-diketiminatosamarium amides and hydrocarbyls
Chunming Cui1, Alexandr Shafir, Joseph A R Schmidt
1Department of Chemistry, University of California, Berkeley, CA 94720, USA.
Abstract:
Reaction of SmCl3 with 1 eq of KL (L =[DippNC(Me)CHC(Me)NDipp]; Dipp = 2,6-i-Pr2C6H3) in THF afforded the dimeric samarium dichloride LSmCl2(THF)Cl2SmL (1) in high yield. Reactions of 1 with NaN(SiMe3)2, KNHAr (Ar = 2,4,6-t-Bu3C6H2), KBHEt3, and KCp*(Cp*= C5Me5) yielded various new complexes: LSmClN(SiMe3)2 (2), LSm[N(SiMe3)2]2 (3), LSmNHAr(HBEt3) (4), LSm(NHAr)2 (5), and LSmCp*Cl (6). Reaction of 1 with one eq of NaN(SiMe3)2 followed by treatment with excess AlMe3 afforded a unique bimetallic samarium tetramer Cl3L2Sm2(AlMe4)2Sm2L2Cl3 (7). Reaction of 6 with LiMe or LiCH2SiMe3 afforded LSmCp*Me (8) and LSmCp*CH2SiMe3 (9) in excellent yield. Methyl abstraction from with B(C6F5)3 in toluene yielded the cationic borate species (LSmCp*)[MeB(C6F5)3] (10). Molecular structures of 1-7 and 9 were determined by X-ray single crystal analysis.
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