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Updated: Aug 18, 2026

Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
Published on: June 14, 2024
SAMs of shape-persistent macrocycles: structure and binding on HOPG and Au(111)
D Borissov1, A Ziegler, S Höger
1University of Karlsruhe, Institute of Physical Chemistry, Kaiserstrasse 12, 76128 Karlsruhe, Germany.
Abstract:
Self-assembled monolayers of shape-persistent macrocycles have been adsorbed on highly oriented pyrolytic graphite and Au(111) substrates. Their structure and binding characteristics have been investigated by scanning tunneling microscopy, X-ray photoelectron spectroscopy, and ultraviolet photoelectron spectroscopy experiments. Special functionalization of the macrocycles for the first time has enabled their self-assembling and binding on a metal substrate and opened a new route for new functional nanostructures.
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