Coherent third-order spectroscopic probes of molecular chirality

Darius Abramavicius1, Shaul Mukamel

  • 1Chemistry Department, University of California, Irvine, CA 92697-2025, USA.

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The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...
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