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Updated: Aug 7, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
Published on: April 4, 2014
Simplified preparation of coniferyl and sinapyl alcohols
1U.S. Dairy Forage Research Center, Agricultural Research Service, U.S. Department of Agriculture, Madison, Wisconsin 53706, USA. hoonkim@wisc.edu
Abstract:
Coniferyl and sinapyl alcohols were prepared from commercially available coniferaldehyde and sinapaldehyde using borohydride exchange resin in methanol. This reduction is highly regioselective and exceptionally simple, making these valuable monolignols readily available to researchers lacking synthetic chemistry expertise.
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