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Related Experiment Videos

Barium chlorite hydrate, Ba(ClO2)2.3.5H2O.

Anton I Smolentsev1, Dmitry Yu Naumov

  • 1Nikolaev Institute of Inorganic Chemistry, SB Russian Academy of Sciences, Akad. Lavrentiev prospekt 3, Novosibirsk 90, 630090 Russia. smolentsev@ngs.ru

Acta Crystallographica. Section C, Crystal Structure Communications
|May 7, 2005
PubMed
Summary

The crystal structure of barium chlorite hydrate, a hydrated inorganic salt, was determined using X-ray analysis. This study reveals the specific arrangement of barium ions, chlorite anions, and water molecules in its monoclinic structure.

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Inorganic chemistry·2021

Area of Science:

  • Inorganic Chemistry
  • Crystallography
  • Solid-State Chemistry

Background:

  • Barium chlorite hydrate is an inorganic compound with the chemical formula Ba(ClO2)2·3.5H2O.
  • Understanding the precise atomic arrangement in crystalline solids is crucial for predicting their physical and chemical properties.

Purpose of the Study:

  • To determine the crystal structure of barium chlorite hydrate at low temperature.
  • To elucidate the coordination environment of the barium cation and the role of water molecules.

Main Methods:

  • Single-crystal X-ray diffraction analysis was performed at 150 K.
  • The crystal structure was solved and refined in the monoclinic space group C2/c.

Main Results:

  • The structure is monoclinic with space group C2/c and Z=8.

Related Experiment Videos

  • Barium ions (Ba2+) are coordinated by chlorite anions (ClO2-) and water molecules, forming layered structures.
  • The barium cation exhibits a coordination number of ten, with a bicapped square antiprism geometry.

    • Conclusions:

    • The detailed crystal structure of barium chlorite hydrate has been established.
    • The study provides insights into the hydration and coordination chemistry of barium chlorites.