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A three-dimensional porous metal-organic framework with the rutile topology constructed from triangular and distorted

Linhua Xie1, Shuxia Liu, Bo Gao

  • 1Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China. liusx@nenu.edu.cn

Chemical Communications (Cambridge, England)
|May 7, 2005
PubMed

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...