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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
06:44

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Published on: March 24, 2018

New family of aminophenalenyl-based neutral radical molecular conductors: synthesis, structure, and solid state

Swadhin K Mandal1, Mikhail E Itkis, Xiaoliu Chi

  • 1Department of Chemistry, University of California, Riverside, California 92521-0403, USA.

Journal of the American Chemical Society
|June 2, 2005
PubMed

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Primary amines react with carbonyl compounds—aldehydes and ketones—to generate imines. Imines consist of a C=N double bond and are named Schiff bases after its discoverer—the German chemist Hugo Schiff. On the other hand, secondary amines react with carbonyl compounds to give enamines. In enamines, the presence of a C=C double bond adjacent to the nitrogen atom leads to the delocalization of the lone pair.
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