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Rubidium gadolinium bis(tungstate).

Kun Peng Wang1, Wen Tao Yu, Jian Xiu Zhang

  • 1State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, People's Republic of China.

Acta Crystallographica. Section C, Crystal Structure Communications
|June 3, 2005
PubMed
Summary

The crystal structure of rubidium gadolinium bis(tungstate) was determined. This reveals a framework of tungsten and gadolinium polyhedra with rubidium ions in the cavities.

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Area of Science:

  • Solid-state chemistry
  • Crystallography
  • Materials science

Background:

  • Rubidium gadolinium bis(tungstate), RbGd(WO4)2, is a material with potential applications in various fields.
  • Understanding its crystal structure is crucial for predicting and optimizing its properties.

Purpose of the Study:

  • To determine the detailed crystal structure of RbGd(WO4)2.
  • To elucidate the coordination environments of the constituent ions and the overall framework.

Main Methods:

  • Single-crystal X-ray diffraction was employed to analyze the crystal structure.
  • The structural model was refined to accurately describe the atomic arrangement.

Main Results:

  • The crystal structure of RbGd(WO4)2 was successfully determined.

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  • The structure features corner- and edge-sharing WO6 octahedra and GdO8 polyhedra, forming a Gd-WO4 backbone.
  • Structural cavities within this backbone are occupied by Rb+ cations.
  • Both Gd and Rb atoms are located on twofold rotation axes.

    • Conclusions:

    • The determined crystal structure provides fundamental insights into the atomic arrangement of RbGd(WO4)2.
    • This structural information is essential for further research into its physical and chemical properties.