Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Bis(thiocarbohydrazide)dithiocyanatoiron(II).

Guang Qi Xiang1, Wei Dong Wang, Mao Lin Hu

  • 1School of Chemistry and Materials Science, Wenzhou Normal College, Zhejiang, Wenzhou 325027, People's Republic of China.

Acta Crystallographica. Section C, Crystal Structure Communications
|June 3, 2005
PubMed
Summary

This study details the crystal structure of a novel iron(II) compound featuring thiocarbohydrazide and thiocyanate ligands. The compound exhibits a distorted octahedral geometry and forms a 3D network through extensive hydrogen bonding.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Red ginseng polysaccharide targets the PI3K/AKT/mTOR pathway to induce mitochondrial apoptosis in bladder cancer.

International journal of biological macromolecules·2026
Same author

Emerging roles and mechanisms of nanoparticles in cancer treatment: innovations and horizons.

Biomedical physics & engineering express·2026
Same author

Andrographolide Promotes Ferroptosis in Pancreatic Cancer via Targeting and Activating HSP90/GPX4 Ubiquitination.

BioFactors (Oxford, England)·2025
Same author

Engineered polyphenol-keratin nanocarriers enhance probiotic delivery and ameliorate obese ulcerative colitis.

Colloids and surfaces. B, Biointerfaces·2025
Same author

α-Lactalbumin based scaffolds for infected wound healing and tissue regeneration.

International journal of pharmaceutics·2024
Same author

Obstructed vein delivery of ceftriaxone via poly(vinyl-pyrrolidone)-iodine-chitosan nanofibers for the management of diabetic foot infections and burn wounds.

International journal of biological macromolecules·2024

Area of Science:

  • Coordination Chemistry
  • Crystallography
  • Materials Science

Background:

  • Iron(II) complexes are crucial in catalysis and materials.
  • Thiocarbohydrazide and thiocyanate are versatile ligands in coordination chemistry.

Purpose of the Study:

  • To synthesize and characterize a new iron(II) complex with thiocarbohydrazide and thiocyanate ligands.
  • To elucidate the coordination geometry and solid-state structure of the title compound.

Main Methods:

  • Single-crystal X-ray diffraction was used to determine the molecular and crystal structure.
  • Analysis of bond lengths, angles, and hydrogen bonding interactions.

Main Results:

  • The iron(II) cation is coordinated by two sulfur atoms and four nitrogen atoms, forming a distorted octahedral geometry.

Related Experiment Videos

  • The thiocarbohydrazide ligand adopts a cis-trans conformation stabilized by intramolecular hydrogen bonds.
  • Intermolecular N-H...S and N-H...N hydrogen bonds link molecules into a 3D network.

    • Conclusions:

    • The synthesized iron(II) complex displays unique structural features due to ligand arrangement and hydrogen bonding.
    • The 3D network structure suggests potential applications in supramolecular chemistry or materials science.