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Related Experiment Videos

Acid neutralization within limestone sand reactors receiving coal mine drainage.

Barnaby J Watten1, Philip L Sibrell, Michael F Schwartz

  • 1United States Geological Survey, Leetown Science Center, 11649 Leetown Road, Kearneysville, WV 25430, USA. barnaby_watten@usgs.gov

Environmental Pollution (Barking, Essex : 1987)
|June 21, 2005
PubMed
Summary

This study shows pulsed bed treatment effectively neutralizes acid mine drainage (AMD) using carbon dioxide (CO2) and limestone, generating alkalinity and removing acidity. The process shows promise for AMD remediation by raising pH and precipitating metals.

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Area of Science:

  • Environmental Engineering
  • Water Treatment Technologies
  • Acid Mine Drainage Remediation

Background:

  • Acid mine drainage (AMD) poses significant environmental challenges due to its acidity and high metal content.
  • Conventional AMD treatment methods can be costly and generate large volumes of sludge.
  • Developing efficient and cost-effective AMD treatment is crucial for environmental protection.

Purpose of the Study:

  • To evaluate the efficacy of pulsed bed treatment for acid mine drainage (AMD).
  • To investigate the role of carbon dioxide (CO2) and intermittent fluidization in AMD neutralization.
  • To assess the process's ability to generate acid neutralization capacity and remove metals.

Main Methods:

  • A prototype pulsed bed reactor with a capacity of 60 L/min was utilized.

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  • Tests involved varying CO2 dosage and fluidization/contraction periods.
  • Field trials were conducted on three different AMD sources.
  • Numerical modeling was employed to optimize CO2 requirements.
  • Main Results:

    • Effective removal of H+ acidity (196-584 mg/L CaCO3) was achieved, with surplus alkalinity generated.
    • Effluent alkalinity correlated with CO2 dosage (DC) via the model Alkalinity=31.22+2.97(DC)0.5.
    • The process raised AMD pH sufficiently to precipitate Fe3+ and Al3+, but not Fe2+ and Mn2+.
    • Altering fluidization parameters impacted energy dissipation and bed expansion but not alkalinity.

    Conclusions:

    • Pulsed bed treatment is a viable technology for neutralizing AMD and generating alkalinity.
    • CO2 requirements can be reduced by increasing AMD acidity and recycling CO2.
    • The process effectively removes key contaminants, offering a promising solution for AMD pollution control.