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Updated: Aug 17, 2026

10:42
Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
Published on: December 29, 2016
Homoleptic uranium(III) imidodiphosphinochalcogenides including the first structurally characterised molecular
Andrew J Gaunt1, Brian L Scott, Mary P Neu
1Actinide, Catalysis, and Separations Chemistry (C-SIC), Chemistry Division, Los Alamos National Laboratory, New Mexico 87545, USA.
Abstract:
Preparation of U[N(EPPh2)2]3 (E = S or Se) by treating U[N(SiMe3)2]3 with three equivalents of NH(EPPh2)2 is described together with presentation of a hitherto unreported molecular crystal structure containing An(III)-Se bonds (An = actinide).
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