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Updated: Aug 16, 2026

Monitoring Pedogenic Inorganic Carbon Accumulation Due to Weathering of Amended Silicate Minerals in Agricultural Soils.
Published on: June 4, 2021
Nitrogen and carbon dioxide adsorption by soils
Peter I Ravikovitch1, Bill W Bogan, Alexander V Neimark
1TRI/Princeton, 601 Prospect Avenue, Princeton, New Jersey 08542, USA. ravikovi@triprinceton.org
Abstract:
High-resolution nitrogen (77 K) and carbon dioxide (273 K) adsorption at subatmospheric pressures has been studied for a range of model soils of various origins with different organic matter (OM) contents. It is demonstrated that N2 and CO2 molecules probe different regions of soil particles. Nitrogen is adsorbed primarily on the outer surface of soil particles, while CO2 has a higher affinity to OM domains. Low-pressure nitrogen adsorption reveals that soil particle surfaces consist of clay/mineral domains with discrete patches of OM. A linear correlation has been found between the CO2 uptake and the amount of organic carbon reduced per unit of the external surface area. A new method for discriminating the microporosity of soil particles and accessibility of OM has been proposed.
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