Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Boron as a bridging ligand.

Holger Braunschweig1, George R Whittell

  • 1Institut für Anorganische Chemie, Bayerische Julius-Maximilians-Universität Würzburg, Germany. h.braunschweig@mail.uni-wuerzburg.de

Chemistry (Weinheim an Der Bergstrasse, Germany)
|August 9, 2005
PubMed
Summary

This study demonstrates the Lewis acidity of iron-boron compounds, enabling the synthesis of novel bimetallic complexes with unique boron coordination. These findings expand the understanding of organometallic chemistry and boron complexation.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Cyclo-Dipnictadialanes.

Angewandte Chemie (International ed. in English)·2021
Same author

Zinc-[7]helicenocyanine and Its Discrete π-Stacked Homochiral Dimer.

Angewandte Chemie (International ed. in English)·2021
Same author

Photoelectron Photoion Coincidence Spectroscopy of NCl<sub>3</sub> and NCl<sub>2</sub>.

Chemphyschem : a European journal of chemical physics and physical chemistry·2021
Same author

The Dimethylbismuth Cation: Entry Into Dative Bi-Bi Bonding and Unconventional Methyl Exchange.

Angewandte Chemie (International ed. in English)·2021
Same author

Efficient energy transport in an organic semiconductor mediated by transient exciton delocalization.

Science advances·2021
Same author

Reactions of diborenes with terminal alkynes: mechanisms of ligand-controlled <i>anti</i>-selective hydroalkynylation, cycloaddition and C[triple bond, length as m-dash]C triple bond scission.

Chemical science·2021

Area of Science:

  • Organometallic Chemistry
  • Inorganic Chemistry
  • Boron Chemistry

Background:

  • The Lewis acidity of metal-boron compounds is crucial for their reactivity.
  • Iron-boron bonds are known for their stability.
  • Understanding boron's coordination chemistry is an ongoing challenge.

Purpose of the Study:

  • To investigate the Lewis acidity of [(eta5-C5R5)Fe(CO)2(BX2)] complexes.
  • To utilize these properties for synthesizing new heterodinuclear boron complexes.
  • To explore unprecedented coordination modes of boron in bimetallic systems.

Main Methods:

  • Reaction of [(eta5-C5R5)Fe(CO)2(BX2)] with 4-methylpyridine to form Lewis acid-base adducts.
  • Synthesis of heterodinuclear bridging borylene, bridging boryl, and mu(2)-boride complexes using analogues.

Related Experiment Videos

  • Characterization of the resulting bimetallic species.

    • Main Results:

    • Demonstrated Lewis acidity of the iron-boron compounds.
    • Successful synthesis of novel heterodinuclear complexes.
    • Observed unprecedented coordination modes for boron in these bimetallic species.

    Conclusions:

    • The Lewis acidity of iron-boron complexes facilitates adduct formation.
    • These complexes serve as versatile precursors for constructing diverse bimetallic boron species.
    • The study reveals novel coordination behaviors of boron in bimetallic frameworks.