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Published on: May 15, 2017
A phenomenological theory of the isotropic to chiral smectic-C phase transition
P K Mukherjee1, H Pleiner, H R Brand
1Haldia Govt. College, P.O.-Debhog, Dist.-East Midnapore, Pin-721657, India.
Abstract:
In this paper we discuss the direct isotropic to chiral smectic-C phase transition on the basis of a phenomenological theory. The model free energy is written in terms of the coupled order parameters including the spontaneous polarization. We present a detailed analysis of the different phases that can occur and analyze the question under which conditions a direct isotropic to chiral smectic-C phase transition is possible when compared to other phase transitions. On the basis of this model the isotropic-smectic-C* transition is always of first order. The theoretical predictions are compared with the available experimental results.
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