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Updated: Jul 21, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
Orientational ordering and dynamics of rodlike polyelectrolytes
Hossein Fazli1, Ramin Golestanian, Mohammad R Kolahchi
1Institute for Advanced Studies in Basic Sciences, Zanjan, Iran.
Abstract:
The interplay between electrostatic interactions and orientational correlations is studied for a model system of charged rods positioned on a chain, using Monte Carlo simulation techniques. It is shown that the coupling brings about the notion of electrostatic frustration, which in turn results in: (i) a rich variety of orientational orderings such as chiral phases, and (ii) an inherently slow dynamics characterized by stretched-exponential behavior in the relaxation functions of the system.
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