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Thermodynamic pressure of a fluid confined in a random porous medium
1Laboratoire de Chimie, UMR 5182 CNRS, Ecole Normale Supérieure de Lyon, France. Wei.Dong@ens.lyon.fr
Abstract:
Up to now, none of the previously derived expressions is usable in simulations for the practical calculation of the thermodynamic pressure of a fluid adsorbed in a random porous medium. A bona fide virial expression of this pressure is presented. Contrary to what was believed, we show that this pressure is a measurable quantity and propose an experimental procedure for its measurement.
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