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Catalysis02:50

Catalysis

The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Precipitation Gravimetry01:03

Precipitation Gravimetry

Precipitation gravimetry is based on converting an analyte into a sparingly soluble precipitate, which is separated by filtration and weighed. An ideal precipitate should be pure, insoluble, of known composition, and easily filtered from the reaction mixture.
In determining nickel by gravimetric analysis, a precipitant of ethanolic dimethylglyoxime is added to a hot nickel salt solution. This is quickly followed by the dropwise addition of dilute ammonia solution until precipitation occurs. A...

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Related Experiment Video

Updated: Jul 16, 2026

Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance
09:02

Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance

Published on: April 27, 2018

New synthesis method for nickel phosphide hydrotreating catalysts.

Shaofeng Yang1, Roel Prins

  • 1Institute for Chemical and Bioengineering, Swiss Federal Institute of Technology (ETH), 8093 Zürich, Switzerland.

Chemical Communications (Cambridge, England)
|August 16, 2005
PubMed
Summary

Researchers developed nickel phosphide particles on silica and alumina supports. This method preserves the small particle sizes of the original metal or metal oxide precursors.

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Area of Science:

  • Materials Science
  • Catalysis
  • Nanotechnology

Background:

  • Nickel phosphide (Ni2P) is a promising catalyst material.
  • Controlling the particle size of catalysts is crucial for optimizing performance.
  • Previous methods for preparing supported nickel phosphides often resulted in larger particle sizes.

Purpose of the Study:

  • To develop a method for preparing small nickel phosphide particles on silica and alumina supports.
  • To investigate the effect of precursor particle size on the final nickel phosphide particle size.
  • To provide a scalable route for producing supported nickel phosphide catalysts.

Main Methods:

  • Nickel or nickel oxide particles were used as precursors.
  • Treatment with phosphine (PH3) and hydrogen (H2) gas.
  • Moderate reaction temperatures were employed.
  • Silica (SiO2) and alumina (Al2O3) were used as support materials.

Main Results:

  • Successfully synthesized nickel phosphide particles on silica and alumina supports.
  • The particle size of the resulting nickel phosphide was equivalent to the precursor particle size.
  • The method allowed for the preparation of small nickel phosphide particles.
  • The morphology of the support material was maintained.

Conclusions:

  • The phosphidation process using phosphine and hydrogen is effective in producing small nickel phosphide particles.
  • This method offers precise control over particle size by utilizing the precursor particle size.
  • The resulting supported nickel phosphide catalysts are suitable for various catalytic applications requiring small active sites.