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A six-bowl carceplex that entraps seven guest molecules
Darren A Makeiff1, John C Sherman
1Department of Chemistry, 2036 Main Mall, University of British Columbia, Vancouver, British Columbia, Canada V6T 1Z1.
Abstract:
A six-bowl carceplex that entraps seven guest molecules, 5.(DMSO)7, was synthesized and characterized. The dynamics of the host shell was studied in solution in the absence and presence of water. A multiple-molecule template was found to drive the formation of 5.(DMSO)x.G(7-x) (G = DMA, DMF; x = 5-7). Higher selectivity was found for species containing greater numbers of DMSO molecules.
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